Product ID:AMERZINE 15 CORROSION INHIBITOR
MSDS Date:01/21/1998
FSC:6810
NIIN:01-052-1651
MSDS Number: CHHQV

ASHLAND CHEMICAL CO DIV OF ASHLAND OIL INC

3849 FISHER RD
COLUMBUS, OH 43228
US

Emergency Phone: 800-274-5263

Info Phone: 614-889-3333

Preparer: THE MSDS CENTER

Cage: 7L600

EMULTEC INDUSTRIAL PRODUCTS INC

CHARROLLTON, TX 75006 US

Telephone: 972-417-1288

Cage: 0WA27

HYDRAZINE (SARA 302/313) (CERCLA)

CAS: 302-01-2

RTECS: MU7175000

OSHA PEL S, 1 PPM

ACGIH TLV: S, 0.01 PPM, A3;9596

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:CAN CAUSE SEVERE EYE IRRITTAION. CAN
CAUSE SKIN IRRITATION. INGESTION, INHALATION OR SKIN ABSORPTION MAY
CAUSE CNS DEPRESSION, KIDNEY DAMAGE, LIVER DAMAGE, BLOOD
ABNORMALITIES. INGESTION MAY CAUSE SEV ERE STOMACH & GI TRACT
IRRITATION. INHALATION MAY CAUSE SEVERE IRRITATION & BURNS TO NOSE,
THROAT, RESPIRATORY TRACT.
Explanation of Carcinogenicity:PER MFR MSDS HYDRAZINE IS LISTED BY IARC
& NTP AS A CARCINOGEN.
Effects of Overexposure:INHALATION/INGESTION/SKIN ABSORPTION:
DIZZINESS, DROWSINESS, WEAKNESS, FATIGUE, NAUSEA, HEADACHE,
UNCONSCIOUSNESS. INHALED-SEVERE IRRITATION/BURNS TO NOSE, THROAT &
RESPIRATORY TRACT. INGESTED-NAUSEA, VOMITING, DIARRHEA, ABDOMINAL
PAIN, VOMITING BLOOD. EYES-BLURRED VISION. SKIN-BLISTERING,
SCALING, SKIN RASH.
Medical Cond Aggravated by Exposure:PREEXISTING DISORDERS OF: SKIN,
LUNGS, LIVER, KIDNEY.

First Aid:EYES-FLUSH WITH WATER FOR 15 MINUTES, HOLD LIDS OPEN. GET
MEDICAL ATTENTION. SKIN-WASH WITH SOAP & WATER. GET MEDICAL
ATTENTION IF SYMPTOMS PERSIST. INHALED-REMOVE TO FRESH AIR. RESTORE
BREATHING AS N EEDED. GET MEDICAL ATTENTION. INGESTED-SEEK
IMMEDIATE MEDICAL ATTENTION; SEK ADVICE ON WHETHER OR NOT TO INDUCE
VOMITING. NOTHING BY MOUTH IF UNCONSCIOUS.

Flash Point:>200F,>93C
Lower Limits:4.7
Upper Limits:99.0
Extinguishing Media:WATER FOG.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND
FULL FACE-PIECE SELF-CONTAINED BREATHING APPARATUS. COOL FIRE
EXPOSED CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:FLAMMABLE AIR-VAPOR MIXTURE MAY
FORM-HYDRAZINE CAN IGNITE SPONTANEOUSLY WHEN DISPERSED IN AIR &
WHEN IN CONTACT WITH POROUS MATERIALS USCH AS EARTH, WOOD, CLOTH

Spill Release Procedures:EVACUATE AREA. COVER WITH SODA ASH OR SODIUM
BICARBONATE. MIX & SPRAY WITH WATER. IF EFFERVESCENT, WAIT UNTIL
REACTION IS COMPLETE. SCOOP INTO CONTAINER. ELIMINATE ALL SOURCES
OF IGNITION. WEAR PROPER PERSONAL PROTECTIVE GEAR.
Neutralizing Agent:SODA ASH, SODIUM BICARBONATE.

Handling and Storage Precautions:DRUMS SHOULD BE STORED ON CONCRETE
PADS WITH LOW CURBS TO CONTROL DRAINAGE. BOND & GROUND ALL
CONTAINERS. STORE BELOW BOILING POINT.
Other Precautions:STORE AWAY FROM IGNITION SOURCES & OXIDANTS,
PREFERABLY OUTDOORS, SHELTERED AGAINST DIRECT SUNLIGHT, DIRT, SNOW,
WATER & ICE ACCUMULATION. IF STORED INDOORS CONTINUOUS VENTILATION
SHOULD BE PROVIDED.

Respiratory Protection:ONLY A NIOSH/MSHA-APPROVED RESPIRATOR IS TO BE
USED IF PEL/TLV EXCEEDED. MONITORING RESULTS MUST BE USED TO ASSESS
THE LEVEL REQUIRED: SELF-CONTAINED BREATHING APPARATUS OR
RESPIRATOR WITH CHEMICAL CA RTRIDGES.
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERALAND/OR LOCAL) EXHAUST
VENTIALTION TO MAINTAIN EXPOSURE BELOW TLV(S).
Protective Gloves:POLYVINYL CHLORIDE (PVC).
Eye Protection:SAFETY GLASSES/CHEMICAL SPLASH GOGGLES.
Other Protective Equipment:TO PREVENT SKIN CONTACT WEAR FULL-BODY
PROTECTIVE CLOTHING. DLA-HMIS: EYE WASH STATION & SAFETY SHOWER.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE
EATING, DRINKING OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
CONTRACT NUMBER: SP045098MCC82.

HCC:T4
Boiling Pt:=100.C, 212.F
Melt/Freeze Pt:=-13.9C, 7.F
Vapor Pres:17.5
Vapor Density:>1.00
Spec Gravity:1.012
pH:11
Evaporation Rate & Reference:<1 (ETHYL ETHER=1)
Appearance and Odor:PALE YELLOW LIQUID. ODOR UNDETERMINED.

Stability Indicator/Materials to Avoid:YES
COPPER COPPER ALLOYS,EXCESSIVE HEAT,LEAD,LEAD ALLOYS,ORGANIC
MATERIALS,STRONG MINERAL ACIDS,STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:AMMONIA, CARBON DIOXIDE, CARBON
MONOXIDE, NITROGEN COMPOUNDS.
Conditions to Avoid Polymerization:PRODUCT WILL NOT UNDERGO HAZARDOUS
POLYMERIZATION.

Waste Disposal Methods:MIX WITH EQUAL VOLUME OF SODA ASH & WATER TO
FORM SLURRY. ADD CALCIUM HYPOCHLORITE, ADD MORE WATER LET, STAND 2
HRS, NEUTRALIZE & FLUSH DOWN DRAIN. DISPOSE OF IN ACCORDANCE WITH
LOCAL, STATE AND FEDER AL REGULATIONS.

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particular situation.